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  1. Transport Canada
  2. CANUTEC
  3. Emergency Response Guidebook 2012
  4. Table 1 - Initial Isolation and Protective Actions Distances

Table 1 - Initial Isolation and Protective Actions Distances (Metric)

  1. The responder should already have:
    • Identified the material by its ID Number and Name; (if an ID Number cannot be found, use the Name of Material index in the blue-bordered pages to locate that number.)
    • Found the three-digit guide for that material in order to consult the emergency actions recommended jointly with this table;
    • Noted the wind direction.
  2. Look in Table 1 (the green-bordered pages) for the ID Number and Name of the Material involved in the incident. Some ID Numbers have more than one shipping name listed - look for the specific name of the material. (If the shipping name is not known and Table 1 lists more than one name for the same ID Number, use the entry with the largest protective action distances.)
  3. Determine if the incident involves a Small or Large spill and if Day or Night. Generally, a Small Spill is one which involves a single, small package (e.g., a drum containing up to approximately 208 liters (55 US gallons), a small cylinder, or a small leak from a large package. A Large Spill is one which involves a spill from a large package, or multiple spills from many small packages. Day is any time after sunrise and before sunset. Night is any time between sunset and sunrise.
  4. Look up the Initial Isolation Distance. Direct all persons to move, in a crosswind direction, away from the spill to the distance specified - in meters and feet.

    Image describing Initial Isolation Distance

  5. Look up the initial Protective Action Distance shown in Table 1. For a given material, spill size, and whether day or night, Table 1 gives the downwind distance - in kilometers and miles - for which protective actions should be considered. For practical purposes, the Protective Action Zone (i.e., the area in which people are at risk of harmful exposure) is a square, whose length and width are the same as the downwind distance shown in Table 1.
  6. Initiate Protective Actions to the extent possible, beginning with those closest to the spill site and working away from the site in the downwind direction. When a water-reactive TIH producing material is spilled into a river or stream, the source of the toxic gas may move with the current or stretch from the spill point downstream for a substantial distance.

    The shape of the area in which protective actions should be taken (the Protective Action Zone) is shown in this figure. The spill is located at the center of the small circle. The larger circle represents the Initial Isolation zone around the spill.

Image describing Protective Action Distance
NOTE 1:
See "Introduction To Green Tables - Initial Isolation And Protective Action Distances" under Factors That May Change the Protective Action Distances
NOTE 2:
See Table 2 - Water-Reactive Materials which Produce Toxic Gases for the list
of gases produced when these materials are spilled in water.

Call the emergency response telephone number listed on the shipping paper or the appropriate response agency as soon as possible for additional information on the material, safety precautions and mitigation procedures.

Change to imperial units

Small SpillsLarge Spills
First Isolate in all directionsThen Protect persons Downwind duringFirst Isolate in all directionsThen Protect persons Downwind during
DayNightDayNight
IDName of Materialmkmkmmkmkm
  2353   Butyryl chloride (when spilled in water)300.10.1300.41
  2382   1,2-Dimethylhydrazine300.20.4600.81.5
  2382   Dimethylhydrazine, symmetrical300.20.4600.81.5
  2395   Isobutyryl chloride (when spilled in water)300.10.1300.20.6
  2407   Isopropyl chloroformate300.10.2600.51
  2417   Carbonyl fluoride1000.62.36003.78
  2417   Carbonyl fluoride, compressed1000.62.36003.78
  2418   Sulfur tetrafluoride1000.52.66003.59.4
  2418   Sulphur tetrafluoride1000.52.66003.59.4
  2420   Hexafluoroacetone600.31.410007.611.0+
  2421   Nitrogen trioxide600.41.83001.96.7
  2434   Dibenzyldichlorosilane (when spilled in water)300.10.1300.20.6
  2435   Ethylphenyldichlorosilane (when spilled in water)300.10.1300.41.1
  2437   Methylphenyldichlorosilane (when spilled in water)300.10.2300.41.4
  2438   Trimethylacetyl chloride300.30.61001.22.1
  2442   Trichloroacetyl chloride300.20.3600.61.2
  2474   Thiophosgene600.723002.75.5
  2477   Methyl isothiocyanate300.10.1300.20.4
  2480   Methyl isocyanate1501.75.8100011.0+11.0+
  2481   Ethyl isocyanate1501.85.9100011.0+11.0+
  2482   n-Propyl isocyanate1001.12.86007.811.0+
  2483   Isopropyl isocyanate1001.23.180010.111.0+
  2484   tert-Butyl isocyanate1001.12.76007.211.0+
  2485   n-Butyl isocyanate600.81.730046.7
  2486   Isobutyl isocyanate600.81.730046.5
  2487   Phenyl isocyanate300.20.3600.81.2
  2488   Cyclohexyl isocyanate300.20.2600.50.7
  2495   Iodine pentafluoride (when spilled in water)300.10.61501.24.6
  2521   Diketene, stabilized300.10.1300.30.5
  2534   Methylchlorosilane300.10.31000.71.8
  2548   Chlorine pentafluoride300.21.23001.87.3
  2600   Carbon monoxide and Hydrogen mixture, compressed300.10.22001.24.8
  2600   Hydrogen and Carbon monoxide mixture, compressed300.10.22001.24.8
  2605   Methoxymethyl isocyanate300.40.51001.21.8
  2606   Methyl orthosilicate300.10.1300.20.3
  2644   Methyl iodide300.10.21000.30.7
  2646   Hexachlorocyclopentadiene300.10.1300.30.4
  2668   Chloroacetonitrile300.10.1300.10.2
  2676   Stibine600.41.73001.96.5
  2691   Phosphorus pentabromide (when spilled in water)300.10.2300.31
  2692   Boron tribromide (when spilled on land)300.10.3300.30.7
  2692   Boron tribromide (when spilled in water)300.10.4600.82.5
  2740   n-Propyl chloroformate300.10.3600.61.1
  2742   sec-Butyl chloroformate300.10.2300.40.6
  2742   Isobutyl chloroformate300.10.2300.30.5
  2743   n-Butyl chloroformate300.10.2300.40.5
  2806   Lithium nitride (when spilled in water)300.10.5600.62.1
  2810   Buzz (when used as a weapon)600.41.74002.28.1
  2810   BZ (when used as a weapon)600.41.74002.28.1
  2810   CS (when used as a weapon)300.10.61000.41.9
  2810   DC (when used as a weapon)300.10.6600.41.8
  2810   GA (when used as a weapon)300.20.21000.50.6
  2810   GB (when used as a weapon)600.41.14002.14.9
  2810   GD (when used as a weapon)600.40.73001.82.7
  2810   GF (when used as a weapon)300.20.31500.81
  2810   H (when used as a weapon)300.10.1600.30.4
  2810   HD (when used as a weapon)300.10.1600.30.4
  2810   HL (when used as a weapon)300.10.31000.51
  2810   HN-1 (when used as a weapon)600.30.52001.11.8
  2810   HN-2 (when used as a weapon)600.30.63001.32.1
  2810   HN-3 (when used as a weapon)300.10.1600.30.3
  2810   L (Lewisite) (when used as a weapon)300.10.31000.51
  2810   Lewisite (when used as a weapon)300.10.31000.51
  2810   Mustard (when used as a weapon)300.10.1600.30.4
  2810   Mustard Lewisite (when used as a weapon)300.10.31000.51
  2810   Poisonous liquid, n.o.s.600.41.32002.35.1
  2810   Poisonous liquid, n.o.s. (Inhalation Hazard Zone A)600.41.32002.35.1
  2810   Poisonous liquid, n.o.s. (Inhalation Hazard Zone B)300.20.2600.50.7
  2810   Poisonous liquid, organic, n.o.s.300.31.13001.84.5
  2810   Poisonous liquid, organic, n.o.s. (Inhalation Hazard Zone A)300.31.13001.84.5

” + ” means distance can be larger in certain atmospheric conditions

Date modified:
2012-08-08