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  1. Transport Canada
  2. CANUTEC
  3. Emergency Response Guidebook 2012
  4. Table 1 - Initial Isolation and Protective Actions Distances

Table 1 - Initial Isolation and Protective Actions Distances (Metric)

  1. The responder should already have:
    • Identified the material by its ID Number and Name; (if an ID Number cannot be found, use the Name of Material index in the blue-bordered pages to locate that number.)
    • Found the three-digit guide for that material in order to consult the emergency actions recommended jointly with this table;
    • Noted the wind direction.
  2. Look in Table 1 (the green-bordered pages) for the ID Number and Name of the Material involved in the incident. Some ID Numbers have more than one shipping name listed - look for the specific name of the material. (If the shipping name is not known and Table 1 lists more than one name for the same ID Number, use the entry with the largest protective action distances.)
  3. Determine if the incident involves a Small or Large spill and if Day or Night. Generally, a Small Spill is one which involves a single, small package (e.g., a drum containing up to approximately 208 liters (55 US gallons), a small cylinder, or a small leak from a large package. A Large Spill is one which involves a spill from a large package, or multiple spills from many small packages. Day is any time after sunrise and before sunset. Night is any time between sunset and sunrise.
  4. Look up the Initial Isolation Distance. Direct all persons to move, in a crosswind direction, away from the spill to the distance specified - in meters and feet.

    Image describing Initial Isolation Distance

  5. Look up the initial Protective Action Distance shown in Table 1. For a given material, spill size, and whether day or night, Table 1 gives the downwind distance - in kilometers and miles - for which protective actions should be considered. For practical purposes, the Protective Action Zone (i.e., the area in which people are at risk of harmful exposure) is a square, whose length and width are the same as the downwind distance shown in Table 1.
  6. Initiate Protective Actions to the extent possible, beginning with those closest to the spill site and working away from the site in the downwind direction. When a water-reactive TIH producing material is spilled into a river or stream, the source of the toxic gas may move with the current or stretch from the spill point downstream for a substantial distance.

    The shape of the area in which protective actions should be taken (the Protective Action Zone) is shown in this figure. The spill is located at the center of the small circle. The larger circle represents the Initial Isolation zone around the spill.

Image describing Protective Action Distance
NOTE 1:
See "Introduction To Green Tables - Initial Isolation And Protective Action Distances" under Factors That May Change the Protective Action Distances
NOTE 2:
See Table 2 - Water-Reactive Materials which Produce Toxic Gases for the list
of gases produced when these materials are spilled in water.

Call the emergency response telephone number listed on the shipping paper or the appropriate response agency as soon as possible for additional information on the material, safety precautions and mitigation procedures.

Change to imperial units

Small SpillsLarge Spills
First Isolate in all directionsThen Protect persons Downwind duringFirst Isolate in all directionsThen Protect persons Downwind during
DayNightDayNight
IDName of Materialmkmkmmkmkm
  1953   Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone C)300.10.320013.2
  1953   Compressed gas, flammable, toxic, n.o.s. (Inhalation Hazard Zone D)300.10.22000.82
  1953   Compressed gas, poisonous, flammable, n.o.s.1000.52.26002.68.6
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A)1000.52.26002.68.6
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B)300.10.33001.33.5
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C)300.10.320013.2
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D)300.10.22000.82
  1953   Compressed gas, toxic, flammable, n.o.s.1000.52.26002.68.6
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A)1000.52.26002.68.6
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B)300.10.33001.33.5
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C)300.10.320013.2
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D)300.10.22000.82
  1955   Compressed gas, poisonous, n.o.s.1000.52.26003.59.4
  1955   Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone A)1000.52.26003.59.4
  1955   Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone B)300.20.83001.54.6
  1955   Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone C)300.10.31500.92.8
  1955   Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone D)300.10.21500.82
  1955   Compressed gas, toxic, n.o.s.1000.52.26003.59.4
  1955   Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone A)1000.52.26003.59.4
  1955   Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone B)300.20.83001.54.6
  1955   Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone C)300.10.31500.92.8
  1955   Compressed gas, toxic, n.o.s. (Inhalation Hazard Zone D)300.10.21500.82
  1955   Organic phosphate compound mixed with compressed gas1000.92.65003.99.4
  1955   Organic phosphate mixed with compressed gas1000.92.65003.99.4
  1955   Organic phosphorus compound mixed with compressed gas1000.92.65003.99.4
  1967   Insecticide gas, poisonous, n.o.s.1000.92.65003.99.4
  1967   Insecticide gas, toxic, n.o.s.1000.92.65003.99.4
  1967   Parathion and compressed gas mixture1000.92.65003.99.4
  1975   Dinitrogen tetroxide and Nitric oxide mixture300.10.61000.62.3
  1975   Nitric oxide and Dinitrogen tetroxide mixture300.10.61000.62.3
  1975   Nitric oxide and Nitrogen dioxide mixture300.10.61000.62.3
  1975   Nitric oxide and Nitrogen tetroxide mixture300.10.61000.62.3
  1975   Nitrogen dioxide and Nitric oxide mixture300.10.61000.62.3
  1975   Nitrogen tetroxide and Nitric oxide mixture300.10.61000.62.3
  1994   Iron pentacarbonyl1000.92.14004.88.3
  2004   Magnesium diamide (when spilled in water)300.10.51000.72.4
  2011   Magnesium phosphide (when spilled in water)600.20.85001.86
  2012   Potassium phosphide (when spilled in water)300.10.63001.24
  2013   Strontium phosphide (when spilled in water)300.10.63001.23.8
  2032   Nitric acid, fuming300.10.31500.51.1
  2032   Nitric acid, red fuming300.10.31500.51.1
  2186 *Hydrogen chloride, refrigerated liquid300.10.330027.6
  2188   Arsine1501410005.811.0+
  2188   SA (when used as a weapon)3001.95.710008.911.0+
  2189   Dichlorosilane300.10.42001.22.9
  2190   Oxygen difluoride2000.42.110002.28.6
  2190   Oxygen difluoride, compressed2000.42.110002.28.6
  2191   Sulfuryl fluoride300.10.53001.95.1
  2191   Sulphuryl fluoride300.10.53001.95.1
  2192   Germane1500.83.28004.410.6
  2194   Selenium hexafluoride2001.13.7800511.0+
  2195   Tellurium hexafluoride2001.24.410006.711.0+
  2196   Tungsten hexafluoride300.20.81500.93.1
  2197   Hydrogen iodide, anhydrous300.10.31500.92.8
  2198   Phosphorus pentafluoride300.20.81500.93.3
  2198   Phosphorus pentafluoride, compressed300.20.81500.93.3
  2199   Phosphine600.214001.34.1
  2202   Hydrogen selenide, anhydrous2001.14.910008.511.0+
  2204   Carbonyl sulfide300.10.33001.33.5
  2204   Carbonyl sulphide300.10.33001.33.5
  2232   Chloroacetaldehyde300.20.4600.71.3
  2232   2-Chloroethanal300.20.4600.71.3
  2308   Nitrosylsulfuric acid (when spilled in water)300.10.43000.92.5
  2308   Nitrosylsulfuric acid, liquid (when spilled in water)300.10.43000.92.5
  2308   Nitrosylsulfuric acid, solid (when spilled in water)300.10.43000.92.5
  2308   Nitrosylsulphuric acid (when spilled in water)300.10.43000.92.5
  2308   Nitrosylsulphuric acid, liquid (when spilled in water)300.10.43000.92.5
  2308   Nitrosylsulphuric acid, solid (when spilled in water)300.10.43000.92.5
  2334   Allylamine300.20.61501.52.8
  2337   Phenyl mercaptan300.10.1300.30.5

” + ” means distance can be larger in certain atmospheric conditions

Date modified:
2012-08-08