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  5. Table 1 - Initial Isolation and Protective Actions Distances

Table 1 - Initial Isolation and Protective Actions Distances

  1. The responder should already have:
    • Identified the material by its ID Number and Name; (if an ID Number cannot be found, use the Name of Material index in the blue-bordered pages to locate that number.)
    • Found the three-digit guide for that material in order to consult the emergency actions recommended jointly with this table;
    • Noted the wind direction.
  2. Look in Table 1 (the green-bordered pages) for the ID Number and Name of the Material involved in the incident. Some ID Numbers have more than one shipping name listed - look for the specific name of the material. (If the shipping name is not known and Table 1 lists more than one name for the same ID Number, use the entry with the largest protective action distances.)
  3. Determine if the incident involves a Small or Large spill and if Day or Night. A Small Spill consists of a release of less than 208 liters (55 US gallons). This generally corresponds to a spill from a single small package (e.g. a drum), a small cylinder, or a small leak from a large package. A Large Spill consists of a release of more than 208 liters (55 US gallons). This usually involves a spill from a large package, or multiple spills from many small packages. Day is any time after sunrise and before sunset. Night is any time between sunset and sunrise.
  4. Look up the Initial Isolation Distance. This distance defines the radius of a zone (Initial Isolation Zone) surrounding the spill in ALL DIRECTIONS. Within this zone, all public should be evacuated (protective clothing and respiratory protection is required in this zone). Persons should be directed to move out of the zone in a direction perpendicular to wind direction (crosswind), and away from the spill, to a minimum distance as prescribed by the Initial Isolation Distance.

    Image describing Initial Isolation Distance

  5. Look up the initial PROTECTIVE ACTION DISTANCE. For a given material, spill size, and whether day or night, Table 1 gives the downwind distance - in kilometers and miles - from the spill/leak source for which protective actions should be considered. For practical purposes, the Protective Action Zone (i.e., the area in which people are at risk of harmful exposure) is a square, whose length and width are the same as the downwind distance shown in Table 1. Protective actions are those steps taken to preserve the health and safety of emergency responders and the public. People in this area should be evacuated and/or sheltered-in-place.
  6. Initiate Protective Actions to the extent possible, beginning with those closest to the spill site and working away from the site in the downwind direction. When a water-reactive TIH (PIH in the US)-producing material is spilled into a river or stream, the source of the toxic gas may move with the current or stretch from the spill point downstream for a substantial distance.

    The shape of the area in which protective actions should be taken (the Protective Action Zone) is shown in this figure. The spill is located at the center of the small circle. The larger circle represents the INITIAL ISOLATION zone around the spill.

Image describing Protective Action Distance
NOTE 1:
See "Introduction To Green Tables - Initial Isolation And Protective Action Distances" under Factors That May Change the Protective Action Distances
NOTE 2:
When a product in Table 1 has the mention "(when spilled in water)", refer to Table 2 - Water-Reactive Materials which Produce Toxic Gases for the list of gases produced when these materials are spilled in water.

Call the emergency response telephone number listed on the shipping paper or the appropriate response agency as soon as possible for additional information on the material, safety precautions and mitigation procedures.

Change to imperial units

Small Spills
(From a small package or small leak from a large package)
Large Spills
(From a large package or from many small packages)
First Isolate in all directionsThen Protect persons Downwind duringFirst Isolate in all directionsThen Protect persons Downwind during
DayNightDayNight
IDName of Materialmkmkmmkmkm
  1766   Dichlorophenyltrichlorosilane (when spilled in water)300.10.2600.61.9
  1767   Diethyldichlorosilane (when spilled in water)300.10.1300.41
  1769   Diphenyldichlorosilane (when spilled in water)300.10.2300.41.2
  1771   Dodecyltrichlorosilane (when spilled in water)300.10.2600.51.3
  1777   Fluorosulfonic acid (when spilled in water)300.10.1300.20.7
  1777   Fluorosulphonic acid (when spilled in water)300.10.1300.20.7
  1781   Hexadecyltrichlorosilane (when spilled in water)300.10.1300.20.6
  1784   Hexyltrichlorosilane (when spilled in water)300.10.2300.41.4
  1799   Nonyltrichlorosilane (when spilled in water)300.10.2600.51.4
  1800   Octadecyltrichlorosilane (when spilled in water)300.10.2300.41.4
  1801   Octyltrichlorosilane (when spilled in water)300.10.2600.51.5
  1804   Phenyltrichlorosilane (when spilled in water)300.10.2300.41.4
  1806   Phosphorus pentachloride (when spilled in water)300.10.2300.41.4
  1808   Phosphorus tribromide (when spilled in water)300.10.3300.41.3
  1809   Phosphorus trichloride (when spilled on land)300.20.51001.12.2
  1809   Phosphorus trichloride (when spilled in water)300.10.3600.72.3
  1810   Phosphorus oxychloride (when spilled on land)300.30.610011.8
  1810   Phosphorus oxychloride (when spilled in water)300.10.2600.62
  1815   Propionyl chloride (when spilled in water)300.10.1300.30.7
  1816   Propyltrichlorosilane (when spilled in water)300.10.2600.61.8
  1818   Silicon tetrachloride (when spilled in water)300.10.3600.82.5
  1828   Sulfur chlorides (when spilled on land)300.10.1600.30.4
  1828   Sulfur chlorides (when spilled in water)300.10.2300.31.1
  1828   Sulphur chlorides (when spilled on land)300.10.1600.30.4
  1828   Sulphur chlorides (when spilled in water)300.10.2300.31.1
  1829   Sulfur trioxide, stabilized600.413002.95.7
  1829   Sulphur trioxide, stabilized600.413002.95.7
  1831   Sulfuric acid, fuming600.413002.95.7
  1831   Sulfuric acid, fuming, with not less than 30% free Sulfur trioxide600.413002.95.7
  1831   Sulphuric acid, fuming600.413002.95.7
  1831   Sulphuric acid, fuming, with not less than 30% free Sulphur trioxide600.413002.95.7
  1834   Sulfuryl chloride (when spilled on land)300.20.4600.81.5
  1834   Sulfuryl chloride (when spilled in water)300.10.2600.51.6
  1834   Sulphuryl chloride (when spilled on land)300.20.4600.81.5
  1834   Sulphuryl chloride (when spilled in water)300.10.2600.51.6
  1836   Thionyl chloride (when spilled on land)300.20.6600.71.5
  1836   Thionyl chloride (when spilled in water)1000.92.46007.911.0+
  1838   Titanium tetrachloride (when spilled on land)300.10.1300.10.2
  1838   Titanium tetrachloride (when spilled in water)300.10.2600.51.6
  1859   Silicon tetrafluoride300.20.71000.51.8
  1859   Silicon tetrafluoride, compressed300.20.71000.51.8
  1892   ED (when used as a weapon)15022.9100010.411.0+
  1892   Ethyldichloroarsine1501.42.14004.66.3
  1898   Acetyl iodide (when spilled in water)300.10.2300.41
  1911   Diborane600.312001.34
  1911   Diborane, compressed600.312001.34
  1911   Diborane mixtures600.312001.34
  1923   Calcium dithionite (when spilled in water)300.20.5600.62.2
  1923   Calcium hydrosulfite (when spilled in water)300.20.5600.62.2
  1923   Calcium hydrosulphite (when spilled in water)300.20.5600.62.2
  1929   Potassium dithionite (when spilled in water)300.10.5600.62
  1929   Potassium hydrosulfite (when spilled in water)300.10.5600.62
  1929   Potassium hydrosulphite (when spilled in water)300.10.5600.62
  1931   Zinc dithionite (when spilled in water)300.10.5600.62
  1931   Zinc hydrosulfite (when spilled in water)300.10.5600.62
  1931   Zinc hydrosulphite (when spilled in water)300.10.5600.62
  1953   Compressed gas, poisonous, flammable, n.o.s.15013.810005.610.2
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone A)15013.810005.610.2
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone B)300.10.42001.22.6
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone C)300.10.31500.92.4
  1953   Compressed gas, poisonous, flammable, n.o.s. (Inhalation Hazard Zone D)300.10.21000.71.9
  1953   Compressed gas, toxic, flammable, n.o.s.15013.810005.610.2
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone A)15013.810005.610.2
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone B)300.10.42001.22.6
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone C)300.10.31500.92.4
  1953   Compressed gas, toxic, flammable, n.o.s. (Inhalation Hazard Zone D)300.10.21000.71.9
  1955   Compressed gas, poisonous, n.o.s.1000.52.510005.610.2
  1955   Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone A)1000.52.510005.610.2
  1955   Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone B)300.20.83001.44.1
  1955   Compressed gas, poisonous, n.o.s. (Inhalation Hazard Zone C)300.10.31500.92.4

” + ” means distance can be larger in certain atmospheric conditions

Date Modified:
2016-08-25