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Hazard Identification Codes Displayed on Some Intermodal Containers

Hazard identification codes, referred to as “hazard identification numbers” (also referred to as the Kemler Code) under European and some South American regulations, may be found in the top half of an orange panel on some intermodal bulk containers. The 4-digit identification number is in the bottom half of the orange panel.

Hazard identification code image

The hazard identification code in the top half of the orange panel consists of two or three digits. In general, the digits indicate the following hazards:

2 - EMISSION OF GAS DUE TO PRESSURE OR CHEMICAL REACTION

3 - FLAMMABILITY OF LIQUIDS (VAPORS) AND GASES OR SELF-HEATING LIQUID

4 - FLAMMABILITY OF SOLIDS OR SELF-HEATING SOLID

5 - OXIDIZING (FIRE-INTENSIFYING) EFFECT

6 - TOXICITY OR RISK OF INFECTION

7 - RADIOACTIVITY

8 - CORROSIVITY

9 - MISCELLANEOUS DANGEROUS SUBSTANCE

  • Doubling of a digit indicates an intensification of that particular hazard (i.e. 33, 66, 88).
  • Where the hazard associated with a material can be adequately indicated by a single digit, the digit is followed by a zero (i.e. 30, 40, 50).
  • A hazard identification code prefixed by the letter “X” indicates that the material will react dangerously with water (i.e. X88).
  • When 9 appears as a 2nd or 3rd digit, this may present a risk of spontaneous violent reaction.

The hazard identification codes listed below have the following meanings:

20
Asphyxiant gas
22
Refrigerated liquefied gas, asphyxiant
223
Refrigerated liquefied gas, flammable
225
Refrigerated liquefied gas, oxidizing (fire-intensifying)
23
Flammable gas
236
Flammable gas, toxic
239
Flammable gas which can spontaneously lead to violent reaction
25
Oxidizing (fire-intensifying) gas
26
Toxic gas
263
Toxic gas, flammable
265
Toxic gas, oxidizing (fire-intensifying)
266
Highly toxic gas
268
Toxic gas, corrosive

30
Flammable liquid
323
Flammable liquid which reacts with water, emitting flammable gas
X323
Flammable liquid which reacts dangerously with water, emitting flammable gas
33
Highly flammable liquid
333
Pyrophoric liquid
X333
Pyrophoric liquid which reacts dangerously with water
336
Highly flammable liquid, toxic
338
Highly flammable liquid, corrosive
X338
Highly flammable liquid, corrosive, which reacts dangerously with water
339
Highly flammable liquid which can spontaneously lead to violent reaction
36
Flammable liquid, toxic, or self-heating liquid, toxic
362
Flammable liquid, toxic, which reacts with water, emitting flammable gas
X362
Flammable liquid, toxic, which reacts dangerously with water, emitting flammable gas
368
Flammable liquid, toxic, corrosive
38
Flammable liquid, corrosive or self-heating liquid, corrosive
382
Flammable liquid, corrosive, which reacts with water, emitting flammable gas
X382
Flammable liquid, corrosive, which reacts dangerously with water, emitting flammable gas
39
Flammable liquid which can spontaneously lead to violent reaction

40
Flammable solid, or self-reactive material, or self-heating material
423
Solid which reacts with water, emitting flammable gas
X423
Flammable solid which reacts dangerously with water, emitting flammable gas
43
Spontaneously flammable (pyrophoric) solid
44
Flammable solid, in the molten state at an elevated temperature
446
Flammable solid, toxic, in the molten state at an elevated temperature
46
Flammable solid, toxic, or self-heating solid, toxic
462
Toxic solid which reacts with water, emitting flammable gas
X462
Solid which reacts dangerously with water, emitting toxic gas
48
Flammable or self-heating solid, corrosive
482
Corrosive solid which reacts with water, emitting flammable gas
X482
Solid which reacts dangerously with water, emitting corrosive gas

50
Oxidizing (fire-intensifying) substance
539
Flammable organic peroxide
55
Strongly oxidizing (fire-intensifying) substance
556
Strongly oxidizing (fire-intensifying) substance, toxic
558
Strongly oxidizing (fire-intensifying) substance, corrosive
559
Strongly oxidizing (fire-intensifying) substance which can spontaneously lead to violent reaction
56
Oxidizing (fire-intensifying) substance, toxic
568
Oxidizing (fire-intensifying) substance, toxic, corrosive
58
Oxidizing (fire-intensifying) substance, corrosive
59
Oxidizing (fire intensifying) substance which can spontaneously lead to violent reaction

60
Toxic material
606
Infectious substance
623
Toxic liquid which reacts with water, emitting flammable gas
63
Toxic liquid, flammable
638
Toxic liquid, flammable, corrosive
639
Toxic liquid, flammable, which can spontaneously lead to violent reaction
64
Toxic solid, flammable or self-heating
642
Toxic solid which reacts with water, emitting flammable gas
65
Toxic material, oxidizing (fire-intensifying)
66
Highly toxic material
663
Highly toxic liquid, flammable
664
Highly toxic solid, flammable or self-heating
665
Highly toxic material, oxidizing (fire-intensifying)
668
Highly toxic material, corrosive
669
Highly toxic material which can spontaneously lead to violent reaction
68
Toxic material, corrosive
69
Toxic material which can spontaneously lead to violent reaction

70
Radioactive material
72
Radioactive gas
723
Radioactive gas, flammable
73
Radioactive liquid, flammable
74
Radioactive solid, flammable
75
Radioactive material, oxidizing (fire-intensifying)
76
Radioactive material, toxic
78
Radioactive material, corrosive

80
Corrosive material
X80
Corrosive material which reacts dangerously with water
823
Corrosive liquid which reacts with water, emitting flammable gas
83
Corrosive liquid, flammable
X83
Corrosive liquid, flammable, which reacts dangerously with water
839
Corrosive liquid, flammable, which can spontaneously lead to violent reaction
X839
Corrosive liquid, flammable, which can spontaneously lead to violent reaction and which reacts dangerously with water
84
Corrosive solid, flammable or self-heating
842
Corrosive solid which reacts with water, emitting flammable gas
85
Corrosive material, oxidizing (fire-intensifying)
856
Corrosive material, oxidizing (fire-intensifying) and toxic
86
Corrosive material, toxic
88
Highly corrosive material
X88
Highly corrosive material which reacts dangerously with water
883
Highly corrosive liquid, flammable
884
Highly corrosive solid, flammable or self-heating
885
Highly corrosive material, oxidizing (fire-intensifying)
886
Highly corrosive material, toxic
X886
Highly corrosive material, toxic, which reacts dangerously with water
89
Corrosive material which can spontaneously lead to violent reaction

90
Miscellaneous dangerous substance; environmentally hazardous substance
99
Miscellaneous dangerous substance transported at elevated temperature