Guide Pages

Initial Isolation and Protective Action Distances (Metric)

Change to Imperial Units

Small SpillsLarge Spills
First Isolate in all directionsThen Protect persons Downwind duringFirst Isolate in all directionsThen Protect persons Downwind during
DayNightDayNight
IDName of Materialmkmkmmkmkm
2199Phosphine600.214001.34.1
 

Name of Material
 
 
Phosphine
 
 
GUIDE
119
GASES - TOXIC - FLAMMABLE
 
POTENTIAL HAZARDS

HEALTH

  • TOXIC; may be fatal if inhaled or absorbed through skin.
  • Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
  • Fire will produce irritating, corrosive and/or toxic gases.
  • Runoff from fire control may cause pollution.

FIRE OR EXPLOSION

  • Flammable; may be ignited by heat, sparks or flames.
  • May form explosive mixtures with air.
  • Those substances designated with a (P) may polymerize explosively when heated or involved in a fire.
  • Vapors from liquefied gas are initially heavier than air and spread along ground.
  • Vapors may travel to source of ignition and flash back.
  • Some of these materials may react violently with water.
  • Cylinders exposed to fire may vent and release toxic and flammable gas through pressure relief devices.
  • Containers may explode when heated.
  • Ruptured cylinders may rocket.
  • Runoff may create fire or explosion hazard.
PUBLIC SAFETY
  • CALL Emergency Response Telephone Number on Shipping Paper first. If Shipping Paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
  • As an immediate precautionary measure, isolate spill or leak area for at least 100 meters (330 feet) in all directions.
  • Keep unauthorized personnel away.
  • Stay upwind.
  • Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks).
  • Keep out of low areas.
  • Ventilate closed spaces before entering.

PROTECTIVE CLOTHING

  • Wear positive pressure self-contained breathing apparatus (SCBA).
  • Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection.
  • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.

EVACUATION

Spill

  • See Table 1 - Initial Isolation and Protective Action Distances for highlighted materials. For non-highlighted materials, increase, in the downwind direction, as necessary, the isolation distance shown under "PUBLIC SAFETY".

Fire

  • If tank, rail car or tank truck is involved in a fire, ISOLATE for 1600 meters (1 mile) in all directions; also, consider initial evacuation for 1600 meters (1 mile) in all directions.
EMERGENCY RESPONSE

FIRE

  • DO NOT EXTINGUISH A LEAKING GAS FIRE UNLESS LEAK CAN BE STOPPED.

Small Fire

  • Dry chemical, CO2, water spray or alcohol-resistant foam.

Large Fire

  • Water spray, fog or alcohol-resistant foam.
  • FOR CHLOROSILANES, DO NOT USE WATER; use AFFF alcohol-resistant medium expansion foam.
  • Move containers from fire area if you can do it without risk.
  • Damaged cylinders should be handled only by specialists.

Fire involving Tanks

  • Fight fire from maximum distance or use unmanned hose holders or monitor nozzles.
  • Cool containers with flooding quantities of water until well after fire is out.
  • Do not direct water at source of leak or safety devices; icing may occur.
  • Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
  • ALWAYS stay away from tanks engulfed in fire.

SPILL OR LEAK

  • ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).
  • All equipment used when handling the product must be grounded.
  • Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire.
  • Do not touch or walk through spilled material.
  • Stop leak if you can do it without risk.
  • Do not direct water at spill or source of leak.
  • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.
  • FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce vapors.
  • If possible, turn leaking containers so that gas escapes rather than liquid.
  • Prevent entry into waterways, sewers, basements or confined areas.
  • Isolate area until gas has dispersed.

FIRST AID

  • Move victim to fresh air.
  • Call 911 or emergency medical service.
  • Give artificial respiration if victim is not breathing.
  • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
  • Administer oxygen if breathing is difficult.
  • Remove and isolate contaminated clothing and shoes.
  • In case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes.
  • In case of contact with liquefied gas, thaw frosted parts with lukewarm water.
  • In case of burns, immediately cool affected skin for as long as possible with cold water. Do not remove clothing if adhering to skin.
  • Keep victim warm and quiet.
  • Keep victim under observation.
  • Effects of contact or inhalation may be delayed.
  • Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.
 
 
 
 
Date modified:
2012-08-08